It might’ve taken a couple of months, but the Vita finally has a Skype app. Signing in is a breeze and just requires you to login once and then make a test call. Both audio and video chats are available, and call quality is fantastic. The app’s layout is very clean and easy to use, and also allows you to pause a game to accept a call. The Skype app is free and available on the PlayStation Store now.
A password will be e-mailed to you.